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SeDoBrEn GoCCe
1) Nitrous oxide is most commonly prepared by careful heating of ammonium nitrate, which decomposes into nitrous oxide and water vapor.
NH
4NO
3(s) → 2 H
2O(g) + N
2O(g)
The addition of various phosphates favors formation of a purer gas at slightly lower temperatures.
This reaction occurs between 170 - 240°C, temperatures where ammonium nitrate is a moderately sensitive explosive and a very powerful oxidizer.
At temperatures much above 240 °C the exothermic reaction may accelerate to the point of detonation. Overheated steam is used to reach the temperature in some production plants.
The mixture must be cooled to avoid such a disaster.
In practice, the reaction involves a series of tedious adjustments to control the temperature to within a narrow range. Professionals have destroyed whole neighborhoods by losing control (of the temperature and pressure in the ammonium nitrate retorts) in commercial scale processes.
Downstream, the hot, corrosive mixture of gases must be cooled to condense the steam and filtered to remove higher oxides of nitrogen.
Also ammonium nitrate smoke, in an extremely persistent colloid will likely have to be removed.
The cleanup is often done in a train of 3 gas washes; namely base, acid and base again.
Any significant amounts of nitric oxide (NO) may not necessarily be absorbed directly by the base (sodium hydroxide) washes.
The nitric oxide impurity is sometimes chelated out with ferrous sulfate, reduced with iron metal, or oxidised and absorbed in base as a higher oxide. The first base wash may (or may not) react out much of the ammonium nitrate smoke, however this reaction generates ammonia gas, which may have to be absorbed in the acid wash.
2) The direct oxidation of ammonia may someday rival the ammonium nitrate pyrolysis synthesis of nitrous oxide mentioned above. This capital-intensive process, which originates in Japan, uses a manganese dioxide-bismuth oxide catalyst:
2 NH
3 + 2 O
2 → N
2O + 3 H
2O
Higher oxides of nitrogen are formed as impurities.
In comparison, uncatalyzed ammonia oxidation (i.e. combustion or explosion) goes primarily to N
2 and H
2O.
3) Nitrous oxide can be made by heating a solution of sulfamic acid and nitric acid. A lot of gas was made this way in Bulgaria.
HNO
3 + NH
2SO
3H → N
2O + H
2SO
4 + H
2O
There is no explosive hazard in this reaction if the mixing rate is controlled. However, as usual, toxic higher oxides of nitrogen form.
4) Nitrous oxide is produced in large volumes as a by-product in the synthesis of adipic acid; one of the two reactants used in nylon manufacture.
This might become a major commercial source, but will require the removal of higher oxides of nitrogen and organic impurities.
Currently much of the gas is decomposed before release for environmental protection.
Greener processes may prevail that substitute hydrogen peroxide for nitric acid oxidation; hence no generation of oxide of nitrogen by-products.
5) Hydroxylammonium chloride can react with sodium nitrite to produce N
2O as well:
NH
3OH+Cl− + NaNO
2 → N
2O + NaCl + H
2O
If the nitrite is added to the hydroxylamine solution, the only remaining byproduct is salt water. However, if the hydroxylamine solution is added to the nitrite solution (nitrite is in excess), then toxic higher oxides of nitrogen are also formed.